Product ID:PLHF1-2X, CUSTOM PLASMA STANDARD, 1,000 PPM (SUPDAT)
MSDS Date:04/15/1996
FSC:6850
NIIN:00N086281
MSDS Number: CHFFV

SPEX CERTIPREP

203 NORCROSS AVE
METUCHEN, NJ 08840
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 732-549-7144

Preparer: SUSHA RAMANE

Cage: 04XT3

SPEX CERTIPREP INC

METUCHEN, NJ 08840 US

Telephone: 732-549-7144

Cage: 04XT3

HYDROCHLORIC ACID; (HCL) (SARA 302/313) (CERCLA)

CAS: 7647-01-0

RTECS: MW4025000

Fraction By Weight: 2-5%

OSHA PEL 5 PPM, C

ACGIH TLV: 5 PPM, C

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

HAFNIUM CHLORIDE OXIDE OCTAHYDRATE; (HFOCL*2-8H*2O) % WT

CAS: 14456-34-9

RTECS: MG4800000

Fraction By Weight: <2.3%

OSHA PEL N/K

ACGIH TLV: N/K

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 90-97%

OSHA PEL N/K

ACGIH TLV: N/K

MEMBS, SKIN & UPPER RESP TRACT. WHEN

RTECS: 9999999ZZ

PRDCES SEVERE BURNS WHICH MAY RSLT IN PRLNGD/PERM

RTECS: 9999999ZZ

SKIN, CONCENTRATED LIQ OR VAP WILL CAUSE REDNESS,

RTECS: 9999999ZZ

MAY CAUSE DERM. EROSION OF TEETH MAY OCCUR W/PRLNGD

RTECS: 9999999ZZ

LIQ CAUSES SEVERE BURNS OF MUC MEMBS OF MOUTH,

RTECS: 9999999ZZ

CONCENTRATED HYDROCHLORIC ACID MAY BE FATAL CAUSING

RTECS: 9999999ZZ

EDEMA OF LARYNX & BRONCHI & CHEM PNEUMIT. SYMPS

RTECS: 9999999ZZ

CHOKING SENSATION. IF INHALED DEEPLY PULMONARY

RTECS: 9999999ZZ

& FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SYMPS & HLTH HAZS FOR DILUTE
HYDROCHLORIC ACID ARE EXPECTED TO BE LESS SEV THAN EXPOS TO
CONCENTRATED HYDROCHLORIC ACID. HOWEVER, SINCE HYDROCHLORIC ACID IS
IN SOLN AT 1% (10,000PPM) OR GREATER, HLTH HAZS FOR CONCENTRATED
HYDROCHLORIC ACIDARE GIVEN. THIS SOLN MAY BE HARMFUL IF INHALED,
INGESTED OR (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: CONTACTED W/SKIN OR EYES. THERE IS
LIMITED INFO AVAIL ON HAFNIUM CMPDS. INHAL MAY BE IRRIT TO LUNG.
INGEST MAY BE HARMFUL. CNTCT W/SKIN OR EYES MAY CAUSE IRRIT.
CONCENTRATED HYDROCHLORIC ACI D MAY BE FATAL IF INHALED, INGESTED
OR ABSORBED THRU SKIN. HYDROCHLORIC ACID VAP/MIST IS IRRITANT OF
EYES, MUC (ING 4)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH W/WATER FOR AT LEAST 15 MINUTES OCCASIONALLY
LIFTING UPPER & LOWER EYELIDS. SKIN: REMOVE CONTAM CLOTHING, THEN
FLUSH W/WATER FOR AT LEAST 15 MINUTES. WASH CLOTHING THOROUGHLY
BEFORE REUSE. INHAL: MOVE TO FRESH AIR. INGEST: DO NOT INDUCE
VOMITING. GET IMMED MEDICAL HELP. IF PATIENT IS CONSCIOUS, GIVE
LARGE QTYS OF WATER OR MILK. IF IRRITATION CONTINUES, GET MEDICAL
ATTN IMMED.

Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.

Spill Release Procedures:VENT AREA. DILUTE SPILL W/WATER & NEUT W/SODA
ASH, LIMESTONE, ETC. WIPE UP & PUT INTO A SEALED CNTNR FOR PROPER
DISPOSAL. WASH SPILL SITE OFF W/WATER AFTER MATL PICKUP IS
COMPLETE. WEAR CHEM RESIST GL ASSES, GLOVES & CLTHG & WEAR NIOSH
APPRVD RESP.
Neutralizing Agent:NEUTRALIZE WITH SODA ASH, LIMESTONE, ETC.

Handling and Storage Precautions:HYDROCHLORIC ACID WILL ATTACK MOST
METALS & SOME FORMS OF PLASTICS, RUBBER & COATINGS. STORE AT ROOM
TEMPERATURE. KEEP TIGHTLY SEALED WHEN NOT IN USE.
Other Precautions:IRRITANT AND CORROSIVE. AVOID INHALATION, INGESTION
AND CONTACT WITH EYES AND SKIN. WASH CAREFULLY AFTER USE.

Respiratory Protection:WEAR NIOSH APPROVED RESPIRATOR.
Ventilation:USE IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 12)
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR CHEMICAL RESISTANT CLOTHING. LAB COAT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO: OF HAFNIUM IN 2% HYDROCHLORIC ACID. MATL TO
AVOID: HYDROCHLORIC ACID COMES INTO CONTACT W/MOST METALS IT
CORRODES THEM SEVERELY & FORMS FLAMMABLE HYDROGEN GAS. CONTACT
W/ANY ALKALI OR ACTIVE METAL MAY DEVELOP ENOUGH HEAT TO CAUSE FIRE
IN ADJACENT COMBUSTIBLE MATERIAL.

Spec Gravity:APPROX 1
Solubility in Water:SOLUBLE
Appearance and Odor:TRANSPARENT WITH AN ACRID ODOR.

Stability Indicator/Materials to Avoid:YES
BASES, AMINES, ALKALI METALS, COPPER, COPPER ALLOYS, ALUMINUM & HCL
CORRODES STEEL. WHEN CONCENTRATED (SUPDAT)
Stability Condition to Avoid:STABLE UNDER NORM STOR & USE. ELEVATED
TEMPS MAY CAUSE CNTNRS TO BURST & LIBERATE TOXIC OXIDES OF HYDROGEN
CHLORIDE GAS.
Hazardous Decomposition Products:WILL RELEASE TOXIC FUMES OF HYDROGEN
CHLORIDE GAS.

Waste Disposal Methods:CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE
DISPOSAL AGENCY FOR FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.